Cédric Slostowski, S. Marre, J. Bassat
Dec 1, 2013
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0
Influential Citations
33
Citations
Journal
Journal of Supercritical Fluids
Abstract
Abstract Cerium-oxide based nanostructures attract increasing interest for their use in multiple applications. In particular, the substitution of Ce atoms by other elements with lower oxidation state is used to control oxygen vacancies within the oxide structures, which can greatly enhance the material properties for catalysis applications. Among the synthesis approaches, supercritical water (scH 2 O) has been proved to be an extremely efficient media for the fast and facile elaboration of pure CeO 2 nanostructures, although substitution was little investigated with this method (precursors’ reactivity, mechanisms, etc.). Here, the influence of two cerium precursors – Ce(NO 3 ) 3 ·6H 2 O and Ce(NO 3 ) 6 (NH 4 ) 2 – in scH 2 O synthesis was first investigated over the CeO 2 nanostructures synthesis process. Cerium ammonium nitrate was later used as precursor for the synthesis of Ce 1− x − y A x B y O 2− δ (A, B = Zr, Pr and/or La; 0 ≤ x , y ≤ 0.1). Supported by ICP analysis quantification, this study proposes an overview of the influences of residence time, temperature and precursors’ concentration over the proportion of the substitution element in the CeO 2 NCs. This work demonstrates a fast and simple process to Ce 1− x − y A x B y O 2− δ nanostructures synthesis using scH 2 O synthesis.