K. Ruhlandt-Senge, R. A. Bartlett, M. Olmstead
Apr 1, 1993
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0
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Journal
Inorganic Chemistry
Abstract
The preparations of some new classes of beryllium compounds that have a coordination number of 3 at beryllium are reported. They were synthesized by the reaction of BeCl 2 (OEt 2 ) 2 with the appropriate lithium salt to give the products (BeMes 2 (OEt 2 )] (1; Mes=2,4,6-Me 3 C 6 H 2 ), (Be(OMes * ) 2 (OEt 2 )] (2; Mes * =2,4,6-t-Bu 3 C 6 H 2 ), and (Be(SMes * ) 2 (THF)].PhMe (3). The compounds were characterized by 1 H NMR and IR spectroscopy, C and H analysis, and X-ray crystallography.