F. Schacher, Jiayin Yuan, H. Schoberth
Apr 20, 2010
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0
Influential Citations
57
Citations
Journal
Polymer
Abstract
Abstract We report on the synthesis and characterization of triblock terpolymers, polybutadiene- block -poly(2-vinyl pyridine)- block -poly( tert -butyl methacrylate) (PB- b -P2VP- b -P t BMA; BVT), via sequential living anionic polymerization in THF at low temperatures using sec -butyl lithium as initiator. In this work, 18 different BVT terpolymers were produced with volume fractions Φ B : Φ V : Φ T in the range of 1 : 0.4…1.2 : 0.2…4.6. All polymers exhibit a very narrow molecular weight distribution (PDI