Y. Wang, Baoyu Guo, Guanglin Jiang
Mar 1, 2011
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Journal
Journal of Chemical Crystallography
Abstract
A new crystal of tetraphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-nickelate acetone solvate (BPNI) has been prepared at room temperature and characterized by elemental analysis, UV–Vis–NIR absorption spectrum and X-ray single crystal determination. The complex crystallized in monoclinic space group P2/c with unit cell dimensions a = 24.5350 (6) Å, b = 7.3097 (2) Å, c = 23.1141 (6) Å, β = 115.585 (2)°, V = 3738.89 (17) Å3, Z = 4, Dx.= 1.5081 (1) g cm−3. The X-ray structure determination revealed that the crystal is centro-symmetrical and there are two halves of independent cations in the molecule.Graphical AbstractA new crystal of tetraphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-nickelate(II) acetone solvate (BPNI) with monoclinic space group P2/c (unit cell dimensions a = 24.5350(6) Å, b = 7.3097(2) Å, c = 23.1141(6) Å, β = 115.585(2)°, V = 3738.89(17) Å3, Z = 4, Dx = 1.5081(1) g cm−3) has been prepared and characterized by elemental analysis, UV–Vis–NIR absorption spectrum and X-ray single crystal determination.