Thomas O. Kurian, Pranita Sadaphale, L. Paliwal
Jul 26, 2013
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Journal
Journal of Chemical Crystallography
Abstract
The title compound 4-{(1E)-1-[(2E)-{[4-(dimethylamino)phenyl]methylidene}hydrazono]ethyl}benzene-1,3-diol (1) which is an azine moiety, has been synthesized by microwave irradiation technique. The characterization by IR and mass spectroscopy confirms the structure of (1). The crystal system, lattice parameters and molecular structure of (1) has been determined by single crystal X-ray diffraction technique. The crystallographic data for the compound (1) is being reported for the first time. Studies reveal that the compound exhibits intermolecular and intramolecular hydrogen bonding interactions in its crystal structure. The compound crystallizes in the monoclinic space group P21/n with unit cell dimensions a = 11.8734(7) Å; b = 9.6194(6) Å; c = 27.2410(16) Å; β = 96.435(3) Å; V = 3091.7(3) Å3 and Dcalc = 1.278 Mg/m3 for Z = 8. The surface morphology of the crystalline compound has been studied by SEM analysis. SEM reveals the microcrystalline features of the compound under study.Graphical AbstractThe azine compound 4-{(1E)-1-[(2E)-{[4-(dimethylamino)phenyl]methylidene}hydrazono]ethyl}benzene-1,3-diol (1) was synthesized by microwave irradiation (MWI) technique and single crystal X-ray diffraction analysis was done and the crystallographic data and studies has been reported..