E. Chistyakov, S. N. Filatov, P. Yudaev
Jan 31, 2019
Citations
0
Influential Citations
2
Citations
Journal
Tetrahedron Letters
Abstract
Abstract 4-(2-(4-((β-Methallyl)oxy)phenyl)propan-2-yl)phenol was prepared via the reaction of methallyl chloride with bisphenol A and used for the synthesis of hexakis-4-(2-(4-((β-methallyl)oxy)phenyl)propan-2-yl)phenoxycyclotriphosphazene. It was revealed that the latter undergoes the Claisen rearrangement and can be also epoxidized by 3-chloroperbenzoic acid. The obtained epoxide was cured by a treatment with isophorone diamine. The decomposition and glass transition temperatures of cured resin were also estimated (275 and 130 °C, respectively) by DSC and TGA methods.