John H. Chen, P. Dorhout
Mar 15, 1997
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Influential Citations
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Journal
Journal of Alloys and Compounds
Abstract
Abstract A family of rare-earth metal selenoantimonates(III) has been prepared by the reaction of the elements in alkali metal polyselenide fluxes or by the metathesis of rare-earth chlorides and alkali metal chalcoantimonates(III). The products are black, fine needles of K2(RE)2−xSb4+[itxSe12 where RE=La, Ce, Pr, and Gd and x~0.33. The compounds were analyzed by single crystal and powder X-ray diffraction, and the praseodymium compound by diffuse reflectance spectroscopy, and magnetic susceptibility. The structure, optical spectrum, and susceptibility data of the praseodymium compound are reported.