Carlos Bustos, C. Manzur, David Carrillo
Mar 1, 1994
Citations
0
Influential Citations
20
Citations
Journal
Inorganic Chemistry
Abstract
In acetonitrile, bis(acetylacetonato)dioxomolybdenum(VI), [MoO 2 (acac) 2 ], reacts with disubstituted hydrazine hydrohalides (RR'NNH 3 + X - : R=R'=Ph; R=Ph, R'= Me; X=Cl, Br, I) to yield a new series of complexes, which have been characterized by elemental analysis, electrochemistry and spectroscopy (IR, UV-visible, and 1 H NMR) and formulated as [Mo(NHNPh 2 )(NNPh 2 )(acac)X 2 ] (X=Cl, Br, I) and [Mo(NHNMePh)-(NNMePh)(acac)X 2 ] (X=Cl, Br, I)