A. Raghu, G. Anita, Y. M. Barigaddi
Apr 5, 2007
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Influential Citations
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Journal
Journal of Applied Polymer Science
Abstract
Four novel polyurethanes (PUs) containing 2,6-bis(4-hydroxybenzylidene) cyclohexanone hard segments with four diisocyanate, namely, 4,4′-diphenylmethane diisocyanate, toluene 2,4-diisocyanate, isophorone diisocyanate, and hexamethylene diisocyanate, were prepared. Structural elucidation and thermal characterization of these PUs were done by Fourier transform infrared, UV, and fluorescence spectroscopy, 1H-NMR, 13C-NMR, and differential thermal analysis/thermogravimetric analysis. All of the PUs contained domains of semicrystalline and amorphous structures as indicated by X-ray diffraction. PUs were soluble in polar aprotic solvents such as N-methyl-2-pyrrolidone, dimethylformamide, and dimethyl sulfoxide. Acoustic properties were calculated from the group contribution method. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007