D. Carmona, F. Lahoz, Sergio Elipe
Oct 16, 2002
Citations
0
Influential Citations
30
Citations
Journal
Organometallics
Abstract
The synthesis and characterization of optically active phosphinooxazoline complexes (RRh and SRh)-[(η5-C5Me5)RhCl(PN)][A] (PN = (4S)-2-(2-diphenylphosphino)phenyl)-4-isopropyl-1,3-oxazoline (PN(iPr)), A = SbF6 (1a,1a‘), A = BF4 (1b,1b‘); PN = (4S)-2-(2-diphenylphosphino)phenyl)-4-methyl-1,3-oxazoline (PN(Me)), A = SbF6 (2a,2a‘), A = BF4 (2b,2b‘); PN = (3aS,8aR)-2-(2-diphenylphosphino)phenyl)-3a,8a-dihydroindane[1,2-d]oxazole] (PN(Ind)), A = SbF6 (3a,3a‘)), (SRh and RRh)-[(η5-C5Me5)RhI(PN(Me))][SbF6] (4a,4a‘) and (RIr and SIr)-[(η5-C5Me5)IrCl(PN)][A] (PN = PN(iPr), A = SbF6 (5a,5a‘), A = BF4 (5b,5b‘); PN = PN(Me), A = SbF6 (6a,6a‘), A = BF4 (6b,6b‘); PN = PN(Ind), A = SbF6 (7a,7a‘)), and the solvate complexes (SRh and RRh)-[(η5-C5Me5)Rh(PN)S][SbF6]2 (PN = PN(iPr) (8a,8a‘), PN(Me) (9a,9a‘), PN(Ind) (10a,10a‘); S = H2O, Me2CO) and (SIr and RIr)-[(η5-C5Me5)Ir(PN)S][A]2 (PN = PN(iPr), A = SbF6 (11a‘), A = BF4 (11b‘); PN = PN(Me), A = SbF6 (12a‘), A = BF4 (12b‘); PN = PN(Ind), A = SbF6 (13a,13a‘)) are reported....