Chen Yuan-tao
2010
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Journal
Chemical Reagents
Abstract
A novel ligand containing sulfonic acid radicals has been synthesized using sodium 2-formylbenzenesulfonate and 3-thiosemicarbazide as starting materials,and a sodium complex was synthesized.The complex was characterized by elemental analysis and IR spectroscopy.The crystal structure of the sodium complex was determined by X-ray single crystal diffractometry.The results showed that the compound was monoclinic,with P2(1)/c,a=0.740 65(5) nm,b=0.873 59(6) nm,c=2.521 00(18) nm,β=98.292 0(10)°,V=1.614 10(19) nm3,Z=4,Mr=388.80,Dc=1.600 g/cm3,T=273(2) K,F(000)=804,μ(MoKa)=0.055 7 cm-1,R=0.054 5,and wR=0.158 8.The complex formed three-dimensional network structure through hydrogen bonds and π-π stacking.