J. Braddock-Wilking, Yanina Levchinsky, N. Rath
Oct 1, 1999
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0
Influential Citations
6
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Journal
Journal of Organometallic Chemistry
Abstract
Abstract The homologous series of primary, secondary and tertiary silanes containing the sterically demanding 2,4,6-trimethoxyphenyl (TMP) group have been prepared in yields ranging from 22 to 45%. The arylsilanes were characterized by multinuclear NMR, IR, GC–MS, elemental analyses, and X-ray crystallography. Relatively short intramolecular distances are observed between Si and the O atoms in the ortho-methoxy groups of the aryl ligand and are shorter than the sum of the van der Waal’s radii in the solid state for all three arylsilanes.