Shengde Wu, Chih-Yi Cheng, Sue‐Lein Wang
1991
Citations
0
Influential Citations
12
Citations
Journal
Inorganic Chemistry
Abstract
The reaction between W(CO) 3 (CH 3 CN) 3 and 1-bromopenta-2,4-diene produces (η 3 -C 5 H 7 )W(CO) 2 (CH 3 CN) 2 Br (1a). Addition of bis(diphenylphosphino)ethane (dppe) and bis(dimethylphosphino)ethane (dmpe) to 1a in CH 2 Cl 2 gives W(PP)(CO) 2 (syn-η 3 -pentadienyl)Br (PP)=dppe, dmpe in high yields