D. Back, Gelson Manzoni de Oliveira, E. S. Lang
Jan 8, 2015
Citations
0
Influential Citations
6
Citations
Journal
Polyhedron
Abstract
Abstract Bis(diphenyl-2-pyridylphosphine)palladium(II) dichloride and bis(triphenylphosphine)palladium(II) dichloride react with (PhTe)2Hg in THF to give the binuclear complexes with tellurolate bridges [PdCl(μ-TePh)PPh2Py]2 (1) (Ph = phenyl; Py = 2-pyridyl) and [PdCl(μ-TePh)PPh3]2 (2). Although no Pd Pd interactions were observed, the tellurium atoms in both complexes attain secondary bonds with a covalent character.