M. Mikuriya, Hideyuki Tsutsumi, Ryoji Nukada
Dec 15, 1996
Citations
0
Influential Citations
13
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
A series of ten trinuclear heterometal complexes with 2-[(3-aminopropyl)amino]ethanethiol (HL), [(MAL2)2MB](ClO4)2·2dmac·2X ([MA, MB] = [Mn, Zn], [Mn, Cd], [Fe, Zn], [Fe, Cd], [Fe, Hg], [Co, Zn] [Co, Cd], [Ni, Zn], [Ni, Cd], [Ni, Hg]; dmac = N,N-dimethylacetamide, X = H2O or CH3OH), have been synthesized and characterized by infrared and electronic spectroscopies, temperature dependence of magnetic susceptibilities (80—300 K), and single-crystal X-ray diffraction technique. Each complex has a thiolato-bridged heterotrinuclear structure which shows a linear arrangement of Oh(MA)–Td(MB)–Oh(MA). The spectral and magnetic properties were discussed in relation to the crystal structures.