P. Balasubramanian, T. Balamurugan, Shen-ming Chen
Jan 1, 2019
Citations
1
Influential Citations
75
Citations
Quality indicators
Journal
Journal of hazardous materials
Abstract
Design and fabrication of cost effective analytical tools to monitor toxic organic emissions in eco system is of a great necessity. Nitrophenols are a class of widespread toxic organic pollutant lead to serious adverse effects in biosphere on its consumption. This article reports a high sensitive, cost effective, robust electrochemical sensor for 4-nitrophenol (4-NP) in environmental water samples. A novel sheet like CoMnO3 (CMO Ns) nanocatalyst was synthesized via oxalic acid assisted co-precipitation technique and employed as electrocatalyst for the high sensitive detection of 4-NP. The physiochemical properties of CMO Ns are studied in detail via XRD, FTIR, TEM, TGA, and XPS. TEM results reviled the protocol is an excellent way for synthesis of a uniformly distributed CMO Ns with lathery surface. Evident to the surface and other physiochemical studies the CMO Ns based sensor holds superior electrocatalytic activity towards 4-NP detection with excellent sensitivity (2.458 μA μM-1 cm-2) coupled with nanomolar detection (10 nm) limits. Moreover, the constructed sensor holds reliable long-term durability, good reproducibility, and excellent working stability. The practical applicability of the developed sensor was evaluated by determination of 4-NP in samples acquired from water resources with RSD ± 3.3%.