G. Minasyan, A. D. Arutyunyan, G. Adamyan
Mar 1, 1994
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Journal
Chemistry of Heterocyclic Compounds
Abstract
Abstract1,3-Diazaadamantanes containing hydrogen atoms or a hydroxyl or oxime group at C(6), under the action of 2 moles of aralkyl halides, are converted in alkaline aqueous media to 3,7-diaralkyl-3, 7-diazabi cyclo(3.3.1]nonanes containing the indicated groups at C(9). Analogously, quaternary salts of 1,3-diaza-adamantanes containing hydrogen atoms or a hydroxyl group at C(6) are converted in an alkaline aqueous medium to the corresponding 3-alkyl-3,7-diazabicyclo[3.3.1]nonanes containing the indicated groups at C(9).