Z. Zhang, X. Bu, Zhi-ang Zhu
Aug 1, 1996
Citations
0
Influential Citations
24
Citations
Journal
Polyhedron
Abstract
Abstract A complex of palladium(II) chloride with tris(2-pyridylmethyl)amine (TPA) has been synthesized and characterized. The single-crystal structure has been determined by X-ray diffraction analysis. The palladium(II) atom in the title complex is in a square planar environment surrounded by three nitrogen atoms of TPA and one chlorine atom, with bond lengths in the range of 2.004–2.012 A for PdN and 2.296 A for PdCl. The properties of [Pd((TPA)Cll)]·ClO 4 have been further studied with IR and UV-vis techniques. IR spectra show that most of the bands of [Pd((TPA)Cl)]·ClO 4 are shifted to lower wavenumbers in comparison with those of the TPA ligand.