N. Kourkoumelis, A. Hatzidimitriou, D. Kovala‐Demertzi
Dec 1, 2006
Citations
0
Influential Citations
1
Citations
Journal
Crystallography Reports
Abstract
The synthesis and molecular structure of di(2-aminopyrimidinium) trichlorodimethyl(2-aminopyrimidine)stannate(IV) chloride (H-2APY)2[SnMe2Cl3(2APY)]Cl is reported. The compound crystallized in the orthorhombic space group Pnma with a = 20.524(1) Å, b = 10.822(1) Å, c = 10.472(1) Å and V = 2325.9(3) Å3, Z = 4. The structure consists of three fragments: the hexacoordinated organotin anionic complex [SnMe2Cl3(2APY)]−, which exhibits distorted octahedral geometry; two protonated 2-aminopyrimidinium cations (H-2APY)+, and one chloride anion.