Chun-lin Ma, G. Tian, Ru-fen Zhang
Apr 1, 2007
Citations
0
Influential Citations
8
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract A new macrocycle dimethyltin(IV) complex 1 has been synthesized by the reaction of 5-phenyl-1,3,4-oxadiazole-2-thiol with dimethyltin dichloride in the presence of sodium ethoxide. The complex 1 has been characterized by elemental, IR, 1 H, 13 C, 119 Sn NMR spectra and X-ray crystallography diffraction analyses. X-ray data reveal that a 24-membered macrocycle associated by intermolecular C S⋯O non-bonded weak interactions. The geometry about each tin atom involved is distorted trigonal bipyramidal.