G. E. Herberich, B. Hessner, S. Beswetherick
Jun 24, 1980
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0
Influential Citations
28
Citations
Journal
Journal of Organometallic Chemistry
Abstract
The synthesis of the organometallic derivative cyclopentadienyl(1,4-dimethyl-1,4-diboracyclohexa-2,5-diene)cobalt is described. This complex, [(CH 3 BC 4 H 4 BCH 3 )Co(η-C 5 H 5 )], forms red-oranged monoclinic crystals, space group P 2 1 / a with Z = 4 in a unit cell of dimensions a 11.362(7), b , 7.467(7), c 13.290(12) A, β 103.76(6)°. The structure has been elucidated by heavy-atom methods from 1732 reflections ( I > 2σ( I )) measured on a Syntex P2 1 four-circle diffractometer and refined to R = 0.055. In the coordination complex all six atoms of the cyclohexadiene ring are within bonding distance of the metal atom, but the two boron atoms bend away from the metal atom, and the ring elongates slightly in the B---B direction. As a standard of comparison the known geometry of the free ligand [1,4-difluoro-1,4-dibora-2,3,5,6-tetramethylcyclohexa-2,5-diene] is used. The terminal methyl groups on the boron atoms, by contrast, bend slightly back towards the metal atom. The cyclopentadienyl ring remains planar but is positionally disordered.