Jelem Restrepo, C. Glidewell, Néstor Cubillán
Feb 5, 2019
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0
Influential Citations
4
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Journal
Journal of Molecular Structure
Abstract
Abstract The compound ethyl 4-hydrazinobenzoate hydrochloride (E-4HB), C9H13N2O2Cl, has been synthesized and characterized by FT-IR, 1H and 13C NMR and X-ray diffraction. The compound crystallizes as colourless plates in the triclinic space group P-1, with Z' = 2 and cell parameters a = 5.9566 (4) A, b = 7.4498 (6) A, c = 23.5349 (17) A, α = 84.323 (3), β = 84.521 (3), γ = 80.257 (3), V = 1020.95 (13) A3. The component ions are linked by two N H⋯N hydrogen bonds and eight N H⋯Cl hydrogen bonds to form complex sheets in which each of the chloride ions accepts hydrogen bonds from four different cations. Calculations on the Non-Covalent Interactions (NCI) amplify the crystallographic conclusions concerning the intermolecular hydrogen bonds.