Wang Jin-tang
2007
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Journal
Journal of Nanjing University of Technology
Abstract
Tris(2,4-di-tert-butyphenyl)phosphate was synthesized with 2,4-di-tert-butyl phenol and phosphorus trichloride in the dimethylbenzene solution.The molecular formula of the compound is C42H63O3P.The data of the crystal structure by Nonius CAD4 X-ray analysis is as follows.The crystal belongs to triclinic,space group P-1 with a=1.3299(3)nm,b=1.3503(3)nm,c=1.3852(3)nm,α=112.20(3)°,β=104.66(3)°,γ=102.31(3)°,Dc=1.027g/cm3,Z=2,F(000)=708,μ=0.098mm-1,the final deviation factor R=0.0965 and wR=0.2450 respectively.X-ray analysis reveals that there are some intramolecular C—H…O hydrogen bonds in the molecule.