J. Ribas, M. Monfort, X. Solans
Feb 1, 1994
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Journal
Inorganic Chemistry
Abstract
The reaction between aqueous solutions of Ni(ClO 4 ) 2 , NaN 3 and 2,2-dimethylpropane-1,3-diamine (Me 2 tn) gives blue-green crystals of the title compound which presents N 3 - in a new coordination mode. The new complex (C 5 H 14 N 8 Ni) n crystallizes in the monoclinic system, space group P2 1 /c, with a=12.649(3) A, b=7.031(2) A, c=12.114(3) A, β=112.39(2) o , V=996.1(8) A 3 , Z=4, R=0.059, and R w =0.059