S. Ren, S.-L. Ma
2009
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Journal
Polish Journal of Chemistry
Abstract
A new μ-dicyanamide (dca) Mn(III) complex, [Mn III (salap)(dca)] n (salap = N,N'-bis(salicylidene)propane-1,2-diamine), has been synthesized and structurally characterized. X-ray diffraction analysis revealed that the complex has a ID zigzag chain structure constructed by μ 1,5 -dca bridge and a Mn III -Schiff base ligand. Magnetic susceptibility measurements indicate the presence of an antiferromagnetic interaction between the intra-chain high-spin Mn(III) ions via the μ 1,5 -dca bridge.