Xie Mei-hua
2009
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Journal
Chinese Journal of Synthetic Chemistry
Abstract
Polysubstituted allylic amine,(Z)-1,3-diphenyl-N,2-ditosyl-2,5-hexadiene-1-amine(1),was synthesized by the three component tandem reaction of allylmagnesium bromide,1-phenyl-2-(p-tosyl)ethyne and N-benzylidene-4-methylbenzenesulfonamide.The structure was characterized by 1H NMR,IR,MS,elemental analysis and X-ray diffraction analysis.The configuration of 1 is in Z-fashion and belongs to monoclinic,space group P2(1)/n with a=11.388 1(2),b=15.297 4(2),c=17.123 8(3),α=90.00°,β=107.62(10)°,γ=90.00°,V=2 843.16(8)3,Z=4,Dc=1.303 g·cm-1,S=1.055.