W. Fu, Jing-Run Shen, Ziwei Tang
Dec 2, 2017
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Journal
Inorganic and Nano-Metal Chemistry
Abstract
ABSTRACT A complex [Ni(meophtpy)2](ClO4)2·2H2O (1) (meophtpy = 4′-(4-methoxyphenyl)-2,2′:6′,2″-terpyridine) has been synthesized and characterized by IR, element analysis, TGA and single crystal X-ray diffraction. The complex crystallizes in Tetragonal system with space group I41/a, a = 24.470(4), b = 24.470(4), c = 13.845(5)Å, V = 8290.12 Å3, Dc = 1.558 g/cm3, Z = 8, F(000) = 4016, final GOF = 1.021, R1 = 0.0619, and wR2 = 0.1261 for 3616 observed reflections with I >2σ(I). The crystal structure analysis shows that a three dimensional network overlapped with terpyridine motifs was formed by hydrogen bonds and π-π interactions which are seldom found in terpyridine complexes. The magnetic property of 1 has also been investigated.