S. Shahzadi, Saqib Ali, A. Badshah
Aug 9, 2006
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Influential Citations
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Journal
Journal of Chemical Crystallography
Abstract
The complex bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8) Å, b=18.7305(16) Å, c=11.9933(10) Å, β=107.074(1)°, V=1857.3(3) Å3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties.