T. Tunç, H. Tezcan, E. Şahin
Jan 1, 2012
Citations
1
Influential Citations
10
Citations
Journal
Molecular Crystals and Liquid Crystals
Abstract
A new Schiff base complex N-(4-bromobenzylidene)-N′-(2-pyridyl) hydrazine, C12H10N3Br, has been synthesized and characterized by elemental analyses, mass, 1H NMR, ultraviolet–visible (UV–VIS), and IR spectroscopy and single-crystal X-ray determination. The p-Br-benzene and pyridine rings are almost planar and the dihedral angle between the planes is 11.1(3)°. The crystal structure is stabilized by intermolecular N‒H…N‒Py hydrogen bonding interaction. X-ray diffraction analyses show that N-(4-bromobenzylidene)-N′-(2-pyridyl) hydrazine Schiff base molecule crystallizes in the monoclinic system, P21/c space group, a = 5.611(5) Å, b = 19.566(5) Å, c = 10.715(5) Å, β = 98.766(5)°, and V = 1162.60(12) Å3.