A. Eremin, D. Vaulina, M. Stepanova
Mar 25, 2011
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Journal
Russian Journal of General Chemistry
Abstract
In this work we present the synthesis and the X-ray crystal analysis (XCA) data of a new palladium(II) mononuclear trifluoroacetate complex [Pd(phen)· (CF3COO)2] (I). Complex I crystallizes in the monoclinic system with P-1 space group; a 8.4941(9), b 19.312(2), c 12.9728(10) A, β 127.46(0)°, V 1689.14(648) A, Z 4, and R 3.85%. The crystal structure of complex I involves stack interactions both between palladium atoms (Pd···Pd 3.322 A) and phenanthroline ligands (π–π interactions, average interplanar distance of 3.42 A) of neighboring molecules.