M. Manukyan
Apr 16, 2015
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Influential Citations
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Journal
Russian Journal of General Chemistry
Abstract
According to the literature data, 3,3-dimethylbutan-2-onyl-substituted dimethylammonium salts containing prop-2-ynyl, but-2-ynyl or 3-phenylprop-2ynyl group underwent 3,2-Stevens rearrangement by the action of basic agents to form allenic aminoketones [4]. In the case of the salts containing ethyl, propyl or butyl group instead of methyl moiety the products of both 3,2and 1,2-Stevens rearrangement were obtained. The 3,2-rearrangement product converted partially into the hydrogenated analogs due to hydride transfer [5].