B. La Ferla, Piergiuliano Bugada, F. Nicotra
May 1, 2006
Citations
0
Influential Citations
10
Citations
Journal
Journal of Carbohydrate Chemistry
Abstract
1‐Methylenphosphonate‐1‐deoxy‐l‐idonojirimycin (1) has been synthesized starting from commercially available tetrabenzyl glucose, the key steps being substitution of the hydroxyl group at C‐5 of compound 7 with an azido group, stereoselective reaction of the aldehyde at C‐1 of compound 10 with dimethyl methylenephosphonate anion, conversion of the azide into an amino group, and finally cyclization of the aminoalcohol 12.