Li Hong-qi
2009
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Journal
Chemical Research
Abstract
A series of 2-silyl-substituted 1,3-benzodithiole compounds were synthesized by metallation reaction and subsequent reaction between lithiated dithiole and chlorosilanes with 1,3-benzodithiole as the starting material.Oxidation potentials of the new compounds were determined.It was found that introduction of silicone led to decrease in the oxidation potential of 1,3-benzodithiole and enhancement of the donating ability of the donors.