Julien Brioche, C. Meyer, J. Cossy
Mar 15, 2013
Citations
0
Influential Citations
29
Citations
Journal
Organic letters
Abstract
The Claisen rearrangement of N-Boc glycinates derived from ynamido-alcohols affords an efficient and stereoselective access to highly functionalized allenamides. These compounds undergo silver-catalyzed cyclization to 3-pyrrolines which are useful precursors for the synthesis of substituted pyrrolidines.