A. A. Prishchenko, M. V. Livantsov, O. Novikova
2010
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0
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Journal
Heteroatom Chemistry
Abstract
The aminomethylation of the several esters of hypophosphorous acid using chloro-, alkoxy-, and amino-substituted methylamines of various structure is proposed as convenient method for the synthesis of new functionalized aminomethylphosphonites and bis(aminomethyl)phosphinates. Also O,O-diethyl(pivaloyl)phosphonite is successfully applied in the aminomethylation as a synthetic analog of unstable diethoxyphosphine. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:361–367, 2010; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20620