B. Jensen, K. Chockalingam
Mar 1, 1986
Citations
0
Influential Citations
6
Citations
Journal
Journal of Heterocyclic Chemistry
Abstract
The total synthesis of a novel benzazepine, 4,5,7a,8-tetrahydro-1,2-dimethoxyphenanthro[10,1-bc]azepin-6(7H)-one is described. Of crucial importance to the preparation of this material was a regiospecific Beckmann rearrangement reaction and the development of an aryl-aryl linkage by a photochemically induced coupling. Details of successful and attempted methodology are reported.