Qiu Kunyuan
1991
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Journal
Acta Polymerica Sinica
Abstract
4-Acetamino-4'-methacryloylaminodiphenylmethane (AMDPM) monomer was synthesized from 4,4'-diaminodiphenylmethane via acetylation reaction and then reacted with methacryloyl chloride. AMDPM monomer was characterized by elemental analysis,1H-NMR and IR spectra. In the presence of 2,2'-azobisisobutyronitrile (AIBN) AMDPM polymerized and formed a brittle homopolymer. The copolymers of methyl acrylate(MA) with AMDPM in various molar ratio were synthesized via free radical polymerization in N,N-dimethylformamide solution. The monomer reactivity ratios were determined by Fineman-Ross method.