T. Kano, R. Kobayashi, K. Maruoka
Jan 4, 2016
Citations
0
Influential Citations
19
Citations
Journal
Organic letters
Abstract
Previously inaccessible N-Boc-protected propargylic and allylic amines were synthesized by the reaction between N-Boc-aminals and organomagnesium reagents through the in situ generated N-Boc-imine intermediates. The obtained N-Boc-propargylic amines could be readily converted into unprecedented N-Boc-ketimines by oxidation with manganese dioxide.