J. Becher, I. Seidel, W. Plass
Jun 12, 2006
Citations
0
Influential Citations
39
Citations
Journal
Tetrahedron
Abstract
Abstract Salicylidene hydrazides represent important ligands forming oxovanadium complexes. Carbohydrate-derived chiral salicylidene hydrazides as ligands for metal ion complexation were synthesized for the first time. The pathway of the mild and selective synthesis starts from commercial saccharides like methyl-α- d -glucopyranoside and methyl-α- d -mannopyranoside. All synthesized carbohydrate-derived salicylidene hydrazides are able to form oxovanadium complexes. The mononuclear structure proposed for the complex of 1,2,3,4-tetra- O -methyl-α- d -glucopyranuronic acid salicylidene hydrazide is consistent with the analytical data (NMR, IR and MS).