A. Dilman, P. Belyakov, A. Korlyukov
Jun 9, 2005
Citations
0
Influential Citations
18
Citations
Journal
Organic letters
Abstract
[reaction: see text] The three-component coupling of aldehydes, secondary amines, and methoxytris(pentafluorophenyl)silane, MeOSi(C(6)F(5))(3), affording pentafluorophenylmethylamines has been described. The generation of the five-coordinate silicate intermediate is believed to be the key feature responsible for the efficiency of the reaction.