I. Ikeda, Hiroshi Watanabe, T. Hirao
Oct 1, 1994
Citations
0
Influential Citations
3
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract Perfluoro-2-methyl-2-pentene was successfully converted to perfluoro-(1,1-dimethylbutyl)methyl ethers by vic -oxymethylfluorination with chloromethyl ethers in the presence of KF in aprotic polar solvents such as N,N -dimethylformamide and N -methylpyrrolidone. By the addition of a catalytic amount of quaternary ammonium salt, the reaction was accelerated and the yield of product greatly increased.