J. Tian, Jinqi Zhang, Xiuzi Shen
Jul 23, 1999
Citations
0
Influential Citations
7
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The one-pot Mannich reaction was used to synthesize 2-( n- morpholinomethyl)-1-phenol ( 1a ), 4-methyl-2-( n- morpholinomethyl)-1-phenol ( 1b ), 4-chloro-2-( n- morpholinomethyl)-1-phenol ( 1c ), 4-nitro-2-( n- morpholinomethyl)-1-phenol ( 1d ), and 1-( n- morpholinomethyl)-naphthol ( 1e ). The dimethylgallium complexes of these compounds have been prepared, and compound 2d has been determined by X-ray crystallography. The complex 2d crystallized with one unit having two identical molecules which have intermolecular contacts between the two phenyls caused by face to face π–π stacking. The Ga–O bond distances are noticeably shorter than in the other dimethylgallium phenoxides reported.