Wataru Kawanobe, K. Yamaguchi, G. Rokicki
Oct 1, 1984
Citations
0
Influential Citations
4
Citations
Journal
Journal of Polymer Science Part A
Abstract
A variety of N-acyl phosphoramidites were prepared from chlorophosphites and amide derivatives, and their structures were determined with the aid of 1H-, 13C-, and 31P-NMR, and IR spectroscopies. These phosphoramidites were employed in direct polycondensation reaction of dicarboxylic acids and diamines under various conditions resulting in polyamides with inherent viscosities of 0.1 to 1.13. The best results were obtained when aliphatic dicarboxylic acids and aromatic diamines were condensed by 2-(N-methylacetamido)-1,3,2-dioxaphospholane in nitriles.