Ju-Yeon Lee, H. Bang, Chang Suk Baek
Jan 31, 2005
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Influential Citations
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Journal
Synthetic Metals
Abstract
Abstract Methyl 2,5-di-(2′-hydroxyethoxy)benzylidenecyanoacetate ( 3 ) was prepared by hydrolysis of methyl 2,5-di-(2′-vinyloxyethoxy)benzylidenecyanoacetate ( 2 ). Diol 3 was condensed with 2,4-toluenediisocyanate (TDI) and 3,3′-dimethoxy-4,4′-biphenylenediisocyanate (DMBPI) to yield novel T-type polyurethanes ( 4 – 5 ) with 2,5-dioxybenzylidenecyanoacetate group as a nonlinear optical (NLO) chromophore, which constitutes a part of the polymer backbone. The resulting polyurethanes 4 – 5 were soluble in common organic solvents such as acetone and dimethylsulfoxide (DMSO). Polymers 4 – 5 showed a thermal stability up to 250 °C in thermogravimetric analysis (TGA) thermograms with glass transition temperature ( T g ) values from differential scanning calorimetry (DSC) thermograms near 145 °C. The second harmonic generation (SHG) coefficients ( d 33 ) of poled polymer films were around 2.36 × 10 −9 esu. These poled polymers exhibited a thermal stability of dipole alignment up to T g , and no SHG decay was observed below 150 °C due to the partial main chain character of the polymer structure, which is acceptable for NLO device applications.