Muge Shele, Xin-Yu Tian, M. Baiyin
Oct 1, 2021
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Influential Citations
7
Citations
Journal
Journal of Solid State Chemistry
Abstract
Abstract Three antimony chalcogenides containing transition metal zinc ions were successfully prepared by solvent method, namely, [Zn(tren)2H]SbSe4 (1) [tren = tris (2 - aminoethyl) amine) ], [Ni(1, 2-dap)3]2Zn(1, 2-dap)Sb2Se8 (2) (1, 2 - dap = 1, 2 - diaminopropane) and Rb2ZnSb4S8 (3). Interestingly, the Zn2+ ion in compound 1 is a trigonal-bipyramidal structure, while in compounds 2 and 3 it is a tetrahedral structure. The optical and photoelectric properties of compounds 1–3 were studied. In addition, the magnetic of compound 2 was studied.