Loomis S. Chen, Grace J. J. Chen, C. Tamborski
Jul 15, 1980
Citations
0
Influential Citations
67
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Experimental conditions have now been developed whereby o -bromophenyllithium(II) may be prepared in excellent yields and used as an organometallic intermediate for the synthesis of a variety of ortho bromo substituted phenyl compounds ( o -BrC 6 H 4 X). THe thermal stability, decomposition products and reactions of II wre studied. REactions between II and a variety of substrates, e.g., CO 2 , dimethylformamide, fluorinated esters, hexafluorobenzene, and organosilicon chlorides were examined.