Ding Feng
2011
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0
Influential Citations
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Journal
Chinese Journal of Explosives and Propellants
Abstract
1,5-Diazido-3-nitrazapentane was synthesized using diethylnitramine dinitrate and sodium azide as starting materials.The kinetic equation describing the synthesis reaction was established.The effect of temperature on the reaction rate was studied.The results indicate that the reaction is of the second order under the experimental conditions,rate constants of the reaction at the temperature of 90,93,95 and 98℃ are 2.11×103,4.72×103,6.55×103,1.20×102 dm3·mol-1·min-1,respectively.The apparent activation energy Ea and pre-exponential factor A of this reaction are 28.87 kJ·mol-1and 7.67×1031min-1,respectively.