Leonid Schwartsburd, M. Iron, L. Konstantinovski
Aug 9, 2010
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Organometallics
Abstract
The complex (PNP)IrI(CH2COCH3) 2 (PNP = 2,6-bis((di-tert-butylphosphino)methyl)pyridine) was prepared by reaction of the dearomatized, electron-rich complex (PNP*)IrI(COE) (1; PNP* = deprotonated PNP, COE = cyclooctene) with acetone. Upon treatment with CO, complex 2 undergoes a surprising elimination of acetone to form the dearomatized species (PNP*)IrI(CO) (4), involving proton migration from the ligand “arm” to the acetonyl moiety. DFT studies reveal that this process occurs via the square-pyramidal intermediate 2+CO, formed upon CO coordination to 2, in which the acetonyl moiety is located at the apical position prior to proton migration. Reaction of 2 with H2 (D2) indicates an equilibrium between complex 2 and the nonaromatic (PNP*)IrIII(H)(CH2COCH3) complex 2b, which is the species that actually activates H2 to exclusively form the trans-dihydride (PNP)IrIII(H)2(CH2COCH3) (5a) and activates D2 to form the trans-hydride−deuteride 5b with benzylic-D incorporation, as also corroborated by DFT studies. ...