J. Cytarska, K. Kaczanowska, M. Zaidlewicz
2007
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Journal
Polish Journal of Chemistry
Abstract
Representative allylic trimethylsilanes and isopropenyltrimethylsilane were hydroborated with dichloroborane, and the products were transformed into the corresponding β-or γ-trimethylsilylboronates. Synthesis of 2-trimethylsilylethylboronic acid and its diethyl ester via hydroboration of trimethylvinylsilane with diisopinocampheylborane, followed by liberation of a-pinene is described.