E. W. Della, Dennis K. Taylor
Jun 1, 1994
Citations
0
Influential Citations
32
Citations
Journal
Journal of Organic Chemistry
Abstract
The synthesis of a wide variety of 1,3-disubstituted bicyclo[1.1.1]pentanes is described, with particular emphasis on the generation of a series of 3-X-substituted bicyclo[1.1.1]pentyl bromides required for solvolytic studies. Functional group manipulation at the bridgehead was readily accomplished in the majority of cases by radical processes; in some instances, transformations were effected via carbanionic-type intermediates